Total Synthesis of (-)-Geissoschizol through Ir-Catalyzed Allylic Amidation as the Key Step

doi:10.1021/acs.orglett.7b03133

	Total Synthesis of (-)-Geissoschizol through Ir-Catalyzed Allylic Amidation as the Key Step
	Zheng, Yu 1,2; Wei, Kun 1; Yang, Yu-Rong1
	2017-12-01
发表期刊	ORGANIC LETTERS
ISSN	1523-7060
卷号	19 期号:23 页码:6460-6462
摘要	The iridium-catalyzed, Zn(OTf)(2) promoted asymmetric allylic amidation of a secondary alcohol derived from tryptamine has been utilized to forge a tetrahydro-beta-carboline. Based on this key step, a novel, facile, and enantioselective total synthesis of (-)-geissoschizol was achieved in 10 steps.
DOI	10.1021/acs.orglett.7b03133
语种	英语
WOS记录号	WOS:000417229000050
引用统计
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/60618
专题	植物化学与西部植物资源持续利用国家重点实验室
作者单位	1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zheng, Yu,Wei, Kun,Yang, Yu-Rong. Total Synthesis of (-)-Geissoschizol through Ir-Catalyzed Allylic Amidation as the Key Step[J]. ORGANIC LETTERS,2017,19(23):6460-6462.
APA	Zheng, Yu,Wei, Kun,&Yang, Yu-Rong.(2017).Total Synthesis of (-)-Geissoschizol through Ir-Catalyzed Allylic Amidation as the Key Step.ORGANIC LETTERS,19(23),6460-6462.
MLA	Zheng, Yu,et al."Total Synthesis of (-)-Geissoschizol through Ir-Catalyzed Allylic Amidation as the Key Step".ORGANIC LETTERS 19.23(2017):6460-6462.

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