Copper-catalyzed synthesis of alpha-amino nitriles through methyl transfer from DMF to aromatic amines | |
Yuan, Zaifeng1,2; Li, Na3; Zhu, Chunyu3; Xia, Chengfeng1,3 | |
2018-03-21 | |
发表期刊 | CHEMICAL COMMUNICATIONS |
ISSN | 1359-7345 |
卷号 | 54期号:23页码:2854-2857 |
摘要 | A copper-catalyzed activation of C(sp(3))-H bonds of DMF at room temperature was developed, which results in methyl transfer to aromatic amines for efficient synthesis of exceedingly valuable alpha-amino nitriles. This process features excellent functional group tolerance, a broad substrate scope, and high activity under ambient conditions. |
DOI | 10.1039/c8cc00485d |
语种 | 英语 |
WOS记录号 | WOS:000428844500006 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.kib.ac.cn/handle/151853/60505 |
专题 | 植物化学与西部植物资源持续利用国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, 132 Lanhei Rd, Kunming 650201, Yunnan, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Yunnan Univ, Sch Chem Sci & Technol, Key Lab Med Chem Nat Resources, Minist Educ & Yunnan Prov, 2 North Cuihu Rd, Kunming 650091, Yunnan, Peoples R China |
推荐引用方式 GB/T 7714 | Yuan, Zaifeng,Li, Na,Zhu, Chunyu,et al. Copper-catalyzed synthesis of alpha-amino nitriles through methyl transfer from DMF to aromatic amines[J]. CHEMICAL COMMUNICATIONS,2018,54(23):2854-2857. |
APA | Yuan, Zaifeng,Li, Na,Zhu, Chunyu,&Xia, Chengfeng.(2018).Copper-catalyzed synthesis of alpha-amino nitriles through methyl transfer from DMF to aromatic amines.CHEMICAL COMMUNICATIONS,54(23),2854-2857. |
MLA | Yuan, Zaifeng,et al."Copper-catalyzed synthesis of alpha-amino nitriles through methyl transfer from DMF to aromatic amines".CHEMICAL COMMUNICATIONS 54.23(2018):2854-2857. |
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