Identification of new qingyangshengenin and caudatin glycosides from the roots of Cynanchum otophyllum | |
Ma, Xiao-Xia1,2; Wang, Dong1; Zhang, Ying-Jun1; Yang, Chong-Ren1 | |
通讯作者 | Zhang, YJ (reprint author), Chinese Acad Sci, State Key Lab Phytochem & Plant Resources W China, Kunming Inst Bot, Kunming 650204, Peoples R China |
2011-09-01 | |
发表期刊 | STEROIDS |
ISSN | 0039-128X |
卷号 | 76期号:10-11页码:1003-1009 |
摘要 | HPLC analysis of the roots of Cynanchum otophyllum Scheind (Asclepiadaceae) led to the isolation of six new pregnane glycosides, specifically otophyllosides N-P (2-4) and otophyllosides Q-S (7-9), in addition to the identification of three known C-21 steroidal glycosides, otophylloside A (1), otophylloside B (5) and caudatin 3-O-beta-D-glucopyranosyl-(1 -> 4)-beta-D-oleandropyranosyl-(1 -> 4)-beta-D-cymaropyranosyl-(1 -> 4)-beta-D-cymaropyranoside (6). The structure of each glycoside was determined by detailed spectroscopic analysis and chemical methods. All compounds contain qingyangshengenin or caudatin aglycones and a straight sugar chain consisting of 4-7 hexosyl moieties with the mode of 1 -> 4 linkage. The optically isomeric monosaccharides, D- and L-cymarose, coexisted in both otophyllosides R (8) and S (9). (C) 2011 Elsevier Inc. All rights reserved. |
关键词 | Cynanchum Otophyllum Asclepiadaceae Pregnane Glycosides Otophyllosides |
学科领域 | Biochemistry & Molecular Biology ; Endocrinology & Metabolism |
DOI | 10.1016/j.steroids.2011.03.019 |
收录类别 | SCI ; IC |
语种 | 英语 |
WOS记录号 | WOS:000294074700008 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.kib.ac.cn/handle/151853/5551 |
专题 | 植物化学与西部植物资源持续利用国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, State Key Lab Phytochem & Plant Resources W China, Kunming Inst Bot, Kunming 650204, Peoples R China 2.Yunnan Univ Tradit Chinese Med, Kunming 650500, Peoples R China |
推荐引用方式 GB/T 7714 | Ma, Xiao-Xia,Wang, Dong,Zhang, Ying-Jun,et al. Identification of new qingyangshengenin and caudatin glycosides from the roots of Cynanchum otophyllum[J]. STEROIDS,2011,76(10-11):1003-1009. |
APA | Ma, Xiao-Xia,Wang, Dong,Zhang, Ying-Jun,&Yang, Chong-Ren.(2011).Identification of new qingyangshengenin and caudatin glycosides from the roots of Cynanchum otophyllum.STEROIDS,76(10-11),1003-1009. |
MLA | Ma, Xiao-Xia,et al."Identification of new qingyangshengenin and caudatin glycosides from the roots of Cynanchum otophyllum".STEROIDS 76.10-11(2011):1003-1009. |
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