Ir-Catalyzed Asymmetric Total Synthesis of (-)-Communesin F
Liang, Xiao1,2; Zhang, Tian-Yuan1,2; Zeng, Xue-Yi1; Zheng, Yu1,2; Wei, Kun1; Yang, Yu-Rong1
2017-03-08
Source PublicationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume139Issue:9Pages:3364-3367
AbstractThe first catalytic asymmetric total synthesis of the heptacyclic alkaloid (-)-communesin F is described. A key step features an iridium-catalyzed asymmetric intermolecular cascade cyclization, constructing the lower N,N-aminal-containing CDEF tetracyclic core in one step. Another notable element is the closure of final ring system (A ring) via a facile reduction of a twisted amide and concomitant cyclization activated by mesylation of N,O-hemiaminal intermediate.
DOI10.1021/jacs.7b00854
Indexed BySCI
Language英语
WOS IDWOS:000396185700015
Citation statistics
Document Type期刊论文
Identifierhttp://ir.kib.ac.cn/handle/151853/50996
Collection植物化学与西部植物资源持续利用国家重点实验室
Affiliation1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Liang, Xiao,Zhang, Tian-Yuan,Zeng, Xue-Yi,et al. Ir-Catalyzed Asymmetric Total Synthesis of (-)-Communesin F[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2017,139(9):3364-3367.
APA Liang, Xiao,Zhang, Tian-Yuan,Zeng, Xue-Yi,Zheng, Yu,Wei, Kun,&Yang, Yu-Rong.(2017).Ir-Catalyzed Asymmetric Total Synthesis of (-)-Communesin F.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,139(9),3364-3367.
MLA Liang, Xiao,et al."Ir-Catalyzed Asymmetric Total Synthesis of (-)-Communesin F".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 139.9(2017):3364-3367.
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