Six New Triterpenoid Glycosides from Gynostemma pentaphyllum
Liu, Jie-Qing2; Wang, Cui-Fang1; Chen, Jian-Chao1; Tu, Shang-Hui3; Gu, Hong-Fei3; Hu, Wen-Xiang2; Qiu, Ming-Hua1
2009
发表期刊HELVETICA CHIMICA ACTA
ISSN0018-019X
卷号92期号:12页码:2737-2745
摘要Six new triterpenoid glycosides, gynosaponins I-VI (1-6, resp.), together with three known compounds, ginseng Rb(1) (7), gypenoside XLIX (8), and gylongiposide I (9), were isolated from the aerial parts of Gynostemma pentaphyllun. Based on ESI-MS, IR, 1D- and 2D-NMR data (HMQC, HMBC, COSY, and TOCSY), the structures of the new compounds were determined as (3 beta,12 beta,20S)-trihydroxydammar-24-ene 20-O-[alpha-rhamnopyranosyl-(1 -> 2)]-beta-glucopyranoside (1), (3 beta,12 beta,20S)-trihydroxydammar-24-ene 20-O-[alpha-rhamnopyranosyl-(1 -> 2)]-alpha-rhamnopyranoside-(1 -> 3)]-beta-glucopyranoside (2), (3 beta,12 beta,20S)-trihydroxydammar-24-ene 3-O-beta-glucopyranosyl-20-O-[alpha-rhamnopyranosyl- 1 -> 2)]-beta-glucopyranoside (3), (3 beta,12 beta,20S)-trihydroxydammar-24-ene 3-O-beta-glucopyranosyl-20-O-[alpha-rhamnopyransoyl-(1 -> 2)][alpha-rhamnopyranosyl-(1 -> 3)]-beta-glucopyranoside (4), (3 beta,12 beta,20S)-trihydroxydammar-24-ene 3-O-{[beta-glucopyranosyl-(1 -> 2)]-beta-glucopyranosyl}-20-O-[alpha-rhamnopyranosyl-(1 -> 2)]-beta-glucopyranoside (5), and (3 beta,12 beta,20S)-trihydroxydammar-24-ene 3-O-{[beta-glucopyranosyl- (1 -> 2)-beta-glucopyranosyl}-20-O-[alpha-rhamnopyransyl-(1 -> 2)][(alpha-rhamnopyranosyl-(1 -> 3)]-beta-glucopyranoside (6).
关键词Chemical-constituents Plants Japonicus
学科领域Chemistry, Multidisciplinary
收录类别SCI ; IC
语种英语
WOS记录号WOS:000273427000010
引用统计
文献类型期刊论文
条目标识符http://ir.kib.ac.cn/handle/151853/4840
专题植物化学与西部植物资源持续利用国家重点实验室
作者单位1.Chinese Acad Sci, State Key Lab Phytochem & Plant Resources W China, Kunming Inst Bot, Kunming 650204, Peoples R China
2.Capital Normal Univ, Coll Life Sci, Beijing 130021, Peoples R China
3.Capital Normal Univ, Dept Chem, Beijing 130021, Peoples R China
推荐引用方式
GB/T 7714
Liu, Jie-Qing,Wang, Cui-Fang,Chen, Jian-Chao,et al. Six New Triterpenoid Glycosides from Gynostemma pentaphyllum[J]. HELVETICA CHIMICA ACTA,2009,92(12):2737-2745.
APA Liu, Jie-Qing.,Wang, Cui-Fang.,Chen, Jian-Chao.,Tu, Shang-Hui.,Gu, Hong-Fei.,...&Qiu, Ming-Hua.(2009).Six New Triterpenoid Glycosides from Gynostemma pentaphyllum.HELVETICA CHIMICA ACTA,92(12),2737-2745.
MLA Liu, Jie-Qing,et al."Six New Triterpenoid Glycosides from Gynostemma pentaphyllum".HELVETICA CHIMICA ACTA 92.12(2009):2737-2745.
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