New triterpenoid glycosides from Centella asiatica
Jiang, ZY; Zhang, XM; Zhou, J; Chen, JJ
2005
发表期刊HELVETICA CHIMICA ACTA
ISSN0018-019X
卷号88期号:2页码:297-303
摘要Four new triterpenoid glycosides named asiaticoside C (1), D (2), E (3), and F (4) were isolated from the BuOH fraction of the EtOH extract of whole plants of Centella asiatica, together with three known compounds, asiaticoside (5), madecassoside (6), and schelfuroside B (7). Based on FAB-MS, IR, H-1- and C-13-NMR, and 2D-NMR data (HMQC, HMBC, COSY), the structures of the new compounds were determined as (2alpha,3beta,4alpha)-23-(acetyloxy)-2,3-dihydroxyurs-12-en-28-oic acid O-alpha-L-rhamnopyranosyl-(1-->4)-O-beta-D-glucopyranosyl-(1-->6)-beta-D-glucopyranosyl ester (1), (2alpha,3beta)-2,3-dihydroxyurs-12-en-28-oic acid O-alpha-L-rhamnopyranosyl-(1-->4)-O-beta-D-glucopyranosyl-(1-->6)-beta-D-glucopyranosyl ester (2), asiatic acid 6-O-beta-D-glycopyranosyl-beta-D-glucopyranosyl ester (3), (3beta,4alpha)-3,23-dihydroxyurs-12-en-28-oic acid O-alpha-L-rhamnopyranosyl-(1-->4)-0-beta-D-glucopyranosyl-(1-->6)-beta-D-glucopyranosyl ester (4).
关键词Maytansinoid Tumor Inhibitors Glycosides Constituents Roots
学科领域Chemistry, Multidisciplinary
收录类别SCI ; IC
语种英语
WOS记录号WOS:000227387200012
引用统计
文献类型期刊论文
条目标识符http://ir.kib.ac.cn/handle/151853/4698
专题植物化学与西部植物资源持续利用国家重点实验室
作者单位Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources W China, Kunming 650204, Yunnan, Peoples R China
推荐引用方式
GB/T 7714
Jiang, ZY,Zhang, XM,Zhou, J,et al. New triterpenoid glycosides from Centella asiatica[J]. HELVETICA CHIMICA ACTA,2005,88(2):297-303.
APA Jiang, ZY,Zhang, XM,Zhou, J,&Chen, JJ.(2005).New triterpenoid glycosides from Centella asiatica.HELVETICA CHIMICA ACTA,88(2),297-303.
MLA Jiang, ZY,et al."New triterpenoid glycosides from Centella asiatica".HELVETICA CHIMICA ACTA 88.2(2005):297-303.
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