Unusual adamantane type polyprenylated acylphloroglucinols with an oxirane unit and their structural transformation from Hypericum hookerianum

doi:10.1016/j.tet.2016.04.025

	Unusual adamantane type polyprenylated acylphloroglucinols with an oxirane unit and their structural transformation from Hypericum hookerianum
	Ye, Ye 1,2; Yang, Xing-Wei1 ; Xu, Gang1
	2016-06-02
发表期刊	TETRAHEDRON
卷号	72 期号:22 页码:3057-3062
摘要	Hookeriones A-D (1-4), adamantane type polycyclic polyprenylated acylphloroglucinols (PPAPs), and hookeriones E-H (5-8), 1,9-seco-adamantane type PPAPs, were isolated from Hypericum hookerianum, along with six known analogues. The structures of 1-8, sharing a common 28,29-epoxide moiety, were determined on the basis of comprehensive NMR and MS spectroscopic data. The biomimetic synthesis of 5-7 from the biogenetically precursors 1-3 was performed, respectively. Absolute configurations of these new PPAPs were further defined by electronic circular dichroism (ECD) and biomimetic synthesis methods. (C) 2016 Published by Elsevier Ltd.
关键词	Polyprenylated Acylphloroglucinol Hypericum Hookerianum Hookeriones A-h Adamantane Oxirane
DOI	10.1016/j.tet.2016.04.025
收录类别	SCI
语种	英语
WOS记录号	WOS:000376703700041
引用统计
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/26262
专题	植物化学与西部植物资源持续利用国家重点实验室
作者单位	1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Ye, Ye,Yang, Xing-Wei,Xu, Gang. Unusual adamantane type polyprenylated acylphloroglucinols with an oxirane unit and their structural transformation from Hypericum hookerianum[J]. TETRAHEDRON,2016,72(22):3057-3062.
APA	Ye, Ye,Yang, Xing-Wei,&Xu, Gang.(2016).Unusual adamantane type polyprenylated acylphloroglucinols with an oxirane unit and their structural transformation from Hypericum hookerianum.TETRAHEDRON,72(22),3057-3062.
MLA	Ye, Ye,et al."Unusual adamantane type polyprenylated acylphloroglucinols with an oxirane unit and their structural transformation from Hypericum hookerianum".TETRAHEDRON 72.22(2016):3057-3062.

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