Curtius-like Rearrangement of an Iron-Nitrenoid Complex and Application in Biomimetic Synthesis of Bisindolylmethanes

doi:10.1021/acs.orglett.6b00864

	Curtius-like Rearrangement of an Iron-Nitrenoid Complex and Application in Biomimetic Synthesis of Bisindolylmethanes
	Li, Dashan 1,3; Wu, Ting 1,3; Lang, Kangjiang 1,3; Xia, Chengfeng 1,2
	2016-05-06
发表期刊	ORGANIC LETTERS
卷号	18 期号:9 页码:2228-2231
摘要	A Curtius-like rearrangement of hydroxamates to isocyanates was discovered. This reaction was initiated from an iron(II)-nitrenoid complex, which was generated by the iron(II)-catalyzed cleavage of N-O bonds of functionalized hydroxamates. To demonstrate the efficiency of this new Curtius-like rearrangement in synthetic chemistry, a biomimetic strategy for the one-pot preparation of bisindolylmethanes was developed.
DOI	10.1021/acs.orglett.6b00864
收录类别	SCI
语种	英语
WOS记录号	WOS:000375891700072
引用统计
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/26247
专题	植物化学与西部植物资源持续利用国家重点实验室
作者单位	1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Peoples R China 2.Yunnan Univ, Key Lab Med Chem Nat Resources, Minist Educ, Kunming 650091, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Li, Dashan,Wu, Ting,Lang, Kangjiang,et al. Curtius-like Rearrangement of an Iron-Nitrenoid Complex and Application in Biomimetic Synthesis of Bisindolylmethanes[J]. ORGANIC LETTERS,2016,18(9):2228-2231.
APA	Li, Dashan,Wu, Ting,Lang, Kangjiang,&Xia, Chengfeng.(2016).Curtius-like Rearrangement of an Iron-Nitrenoid Complex and Application in Biomimetic Synthesis of Bisindolylmethanes.ORGANIC LETTERS,18(9),2228-2231.
MLA	Li, Dashan,et al."Curtius-like Rearrangement of an Iron-Nitrenoid Complex and Application in Biomimetic Synthesis of Bisindolylmethanes".ORGANIC LETTERS 18.9(2016):2228-2231.

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