Iridium-catalyzed enantioselective allylation of silyl enol ethers derived from ketones and alpha,beta-unsaturated ketone

doi:10.1039/c5cc07221b

	Iridium-catalyzed enantioselective allylation of silyl enol ethers derived from ketones and alpha,beta-unsaturated ketone
	Liang, Xiao; Wei, Kun; Yang, Yu-Rong
	2015
发表期刊	CHEMICAL COMMUNICATIONS
卷号	51 期号:98 页码:17471-17474
摘要	The unified Ir-catalyzed enantioselective allylic substitution reactions of silyl enol ethers derived from ketones and alpha,beta-unsaturated ketones with branched, racemic allylic alcohols are described. This transformation is catalyzed by the Carreira system and proceeds without fluoride, and with high ee and b : l ratio. The synthetic utility of this method was illustrated by the concise enantioselective total synthesis of marine natural products calyxolane A, B and by the assignment of the absolute configuration of calyxolane A.
DOI	10.1039/c5cc07221b
收录类别	SCI
语种	英语
WOS记录号	WOS:000365401300028
引用统计	被引频次：35[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/25244
专题	植物化学与西部植物资源持续利用国家重点实验室
推荐引用方式 GB/T 7714	Liang, Xiao,Wei, Kun,Yang, Yu-Rong. Iridium-catalyzed enantioselective allylation of silyl enol ethers derived from ketones and alpha,beta-unsaturated ketone[J]. CHEMICAL COMMUNICATIONS,2015,51(98):17471-17474.
APA	Liang, Xiao,Wei, Kun,&Yang, Yu-Rong.(2015).Iridium-catalyzed enantioselective allylation of silyl enol ethers derived from ketones and alpha,beta-unsaturated ketone.CHEMICAL COMMUNICATIONS,51(98),17471-17474.
MLA	Liang, Xiao,et al."Iridium-catalyzed enantioselective allylation of silyl enol ethers derived from ketones and alpha,beta-unsaturated ketone".CHEMICAL COMMUNICATIONS 51.98(2015):17471-17474.

条目包含的文件		下载所有文件
文件名称/大小	文献类型	版本类型	开放类型	使用许可
liang2015.pdf（757KB）	期刊论文	作者接受稿	开放获取	CC BY-NC-SA	浏览下载