Iridium-catalyzed enantioselective synthesis of (-)- and (+)-aurantioclavine

doi:10.1016/j.tetlet.2015.09.039

	Iridium-catalyzed enantioselective synthesis of (-)- and (+)-aurantioclavine
	Lei,Ting; Zhang,Hongbin; Yang,Yu-Rong
	2015-10-21
发表期刊	TETRAHEDRON LETTERS
卷号	56 期号:43 页码:5933-5936
摘要	A new protocol for generating indoleazepine 9 via an Ir-catalyzed intramolecularly asymmetric amination of secondary allylic alcohol 5 in the presence of Carreira ligand (10) and Sc(OTf)(3) is described. This methodology has been exploited in the facile synthesis of natural (-)-aurantioclavine (1), a biosynthetical precursor of communesins, and its unnatural enantiomer (+)-aurantioclavine (ent-1). (C) 2015 Elsevier Ltd. All rights reserved.
关键词	Iridium-catalyzed Asymmetric Amination Aurantioclavine
DOI	10.1016/j.tetlet.2015.09.039
收录类别	SCI
语种	英语
WOS记录号	WOS:000362919100025
引用统计	被引频次：27[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/25205
专题	植物化学与西部植物资源持续利用国家重点实验室
推荐引用方式 GB/T 7714	Lei,Ting,Zhang,Hongbin,Yang,Yu-Rong. Iridium-catalyzed enantioselective synthesis of (-)- and (+)-aurantioclavine[J]. TETRAHEDRON LETTERS,2015,56(43):5933-5936.
APA	Lei,Ting,Zhang,Hongbin,&Yang,Yu-Rong.(2015).Iridium-catalyzed enantioselective synthesis of (-)- and (+)-aurantioclavine.TETRAHEDRON LETTERS,56(43),5933-5936.
MLA	Lei,Ting,et al."Iridium-catalyzed enantioselective synthesis of (-)- and (+)-aurantioclavine".TETRAHEDRON LETTERS 56.43(2015):5933-5936.

条目包含的文件		下载所有文件
文件名称/大小	文献类型	版本类型	开放类型	使用许可
1-s2.0-S004040391530（660KB）	期刊论文	作者接受稿	开放获取	CC BY-NC-SA	浏览下载