A pair of unprecedented cyclohexylethanoid enantiomers containing unusual trioxabicyclo[4.2.1]nonane ring from Clerodendrum bungei

doi:10.1016/j.tetlet.2014.02.088

	A pair of unprecedented cyclohexylethanoid enantiomers containing unusual trioxabicyclo[4.2.1]nonane ring from Clerodendrum bungei
	Zhu, Hucheng 1; Huan, Lijun 2; Chen, Chunmei 1; Yang, Jing3 ; He, Jiangbo 4; Chen, Yong 2; Yao, Guangmin 1; Luo, Zengwei 1; Xue, Yongbo 1; Zhang, Yonghui 1
通讯作者	Xue,YB (reprint author),Huazhong Univ Sci & Technol,Tongi Med Coll,Sch Pharm,Hubei Key Lab Nat Med Chem & Resource Evaluat,Wuhan 430030,Peoples R China. ; yongboxue@mail.hust.edu.cn ; zhangyh@mails.tjmu.edu.cn
	2014-04-02
发表期刊	TETRAHEDRON LETTERS
ISSN	0040-4039
卷号	55 期号:14 页码:2277-2279
摘要	A pair of unprecedented enantiomers (1a/1b) of cyclohexylethanoid bearing an unusual trioxabicyclo[4.2.1]nonane ring, along with two known structurally related cyclohexylethanoids, (+)-rengyolone (2) and cleroindicin E (3), were isolated from the aerial parts of Clerodendrum bungei. The structures and absolute configurations of the enantiomers were determined by comprehensive spectroscopic analysis, single-crystal X-ray diffraction, and quantum mechanical calculation of the electronic circular dichroic (ECD) spectra. The postulated biogenetic pathway of 1a/1b was also discussed. (C) 2014 Elsevier Ltd. All rights reserved.
关键词	Clerodendrum Bungei Enantiomer X-ray Ecd
学科领域	Chemistry
DOI	10.1016/j.tetlet.2014.02.088
收录类别	SCI ; IC
语种	英语
WOS记录号	WOS:000334817900026
引用统计
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/18129
专题	植物化学与西部植物资源持续利用国家重点实验室
作者单位	1.Huazhong Univ Sci & Technol, Tongi Med Coll, Sch Pharm, Hubei Key Lab Nat Med Chem & Resource Evaluat, Wuhan 430030, Peoples R China 2.Hubei Univ, Coll Life Sci, Wuhan 430062, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China 4.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650204, Peoples R China
推荐引用方式 GB/T 7714	Zhu, Hucheng,Huan, Lijun,Chen, Chunmei,et al. A pair of unprecedented cyclohexylethanoid enantiomers containing unusual trioxabicyclo[4.2.1]nonane ring from Clerodendrum bungei[J]. TETRAHEDRON LETTERS,2014,55(14):2277-2279.
APA	Zhu, Hucheng.,Huan, Lijun.,Chen, Chunmei.,Yang, Jing.,He, Jiangbo.,...&Zhang, Yonghui.(2014).A pair of unprecedented cyclohexylethanoid enantiomers containing unusual trioxabicyclo[4.2.1]nonane ring from Clerodendrum bungei.TETRAHEDRON LETTERS,55(14),2277-2279.
MLA	Zhu, Hucheng,et al."A pair of unprecedented cyclohexylethanoid enantiomers containing unusual trioxabicyclo[4.2.1]nonane ring from Clerodendrum bungei".TETRAHEDRON LETTERS 55.14(2014):2277-2279.

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