Twelve new compounds from Ligularia melanothyrsa; isolation of melanothyrsins A-E, normelanothyrsin A, and other eremophilane sesquiterpenoids
Saito, Yoshinori1; Ichihara, Mayu1; Okamoto, Yasuko1; Gong, Xun2; Kuroda, Chiaki3,4; Tori, Motoo1
通讯作者Gong, X (reprint author), Chinese Acad Sci, Kunming Inst Bot, Kunming 650204, Peoples R China. ; gongxun@mail.kib.ac.cn ; chkkuroda@rikkyo.ac.jp ; tori@ph.bunri-u.ac.jp
2014-04-22
发表期刊TETRAHEDRON
ISSN0040-4020
卷号70期号:16页码:2621-2628
摘要Twelve new compounds, namely, five melanothyrsins A-E (1 alpha-angeloyloxyeremophilenolides), normelanothyrsin A (1 alpha-angeloyloxynoreremophilenone), and six other eremophilane-type compounds, have been isolated from Ligularia melanothyrsa Hand.-Mazz. (Asteraceae), collected in the Sichuan Province of China. Six of the compounds have a 1 alpha-angeloyloxy moiety, while the other six have no functional group at the C-1 position. The absolute configuration was also determined using CD spectra. This is the first chemical study of compounds isolated from this species. (C) 2014 Elsevier Ltd. All rights reserved.
关键词Asteraceae Ligularia Melanothyrsa Sesquiterpenoid e Eremophilanolide Melanothyrsin
学科领域Chemistry, Organic
DOI10.1016/j.tet.2014.02.080
收录类别SCI ; IC
语种英语
WOS记录号WOS:000334144500003
引用统计
文献类型期刊论文
条目标识符http://ir.kib.ac.cn/handle/151853/18057
专题资源植物与生物技术所级重点实验室
作者单位1.Tokushima Bunri Univ, Fac Pharmaceut Sci, Yamashiro, Tokushima 7708514, Japan
2.Chinese Acad Sci, Kunming Inst Bot, Kunming 650204, Peoples R China
3.Rikkyo Univ, Dept Chem, Toshima Ku, Tokyo 1718501, Japan
4.Rikkyo Univ, Res Ctr Smart Mol, Toshima Ku, Tokyo 1718501, Japan
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Saito, Yoshinori,Ichihara, Mayu,Okamoto, Yasuko,et al. Twelve new compounds from Ligularia melanothyrsa; isolation of melanothyrsins A-E, normelanothyrsin A, and other eremophilane sesquiterpenoids[J]. TETRAHEDRON,2014,70(16):2621-2628.
APA Saito, Yoshinori,Ichihara, Mayu,Okamoto, Yasuko,Gong, Xun,Kuroda, Chiaki,&Tori, Motoo.(2014).Twelve new compounds from Ligularia melanothyrsa; isolation of melanothyrsins A-E, normelanothyrsin A, and other eremophilane sesquiterpenoids.TETRAHEDRON,70(16),2621-2628.
MLA Saito, Yoshinori,et al."Twelve new compounds from Ligularia melanothyrsa; isolation of melanothyrsins A-E, normelanothyrsin A, and other eremophilane sesquiterpenoids".TETRAHEDRON 70.16(2014):2621-2628.
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