| Tackling Reactivity and Selectivity within a Strained Architecture: Construction of the [6-6-5-7] Tetracyclic Core of Calyciphylline Alkaloids | |
Xu, Chen2; Wang, Lu2; Hao, Xiaojiang1 ; Wang, David Zhigang2
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| 通讯作者 | Hao, XJ (reprint author), Chinese Acad Sci, Kunming Inst Bot, Kunming 650204, Peoples R China. ; haoxj@mail.kib.ac.cn ; dzw@pkusz.edu.cn |
| 2012-07-20 | |
| 发表期刊 | JOURNAL OF ORGANIC CHEMISTRY
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| ISSN | 0022-3263 |
| 卷号 | 77期号:14页码:6307-6313 |
| 摘要 | A stereochemically controlled route to the enantiopure [6-6-5-7] tetracyclic core of Calyciphylline A class alkaloids was established, which involves Overman rearrangement, [2 + 2] photochemical cycloaddition, Grob fragmentation, C-N bond-forming nucleophilic displacement, and ring strain-directed hydrogenation as strategic steps. |
| 关键词 | 1st Total Syntheses Daphniphyllum-calycinum Longeracemosum Fragmentation |
| 学科领域 | Chemistry, Organic |
| DOI | 10.1021/jo300776d |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000306534400046 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.kib.ac.cn/handle/151853/15087 |
| 专题 | 植物化学与西部植物资源持续利用国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Kunming Inst Bot, Kunming 650204, Peoples R China 2.Peking Univ, Shenzhen Grad Sch, Sch Chem Biol & Biotechnol, Lab Chem Genom, Shenzhen 518055, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Chen,Wang, Lu,Hao, Xiaojiang,et al. Tackling Reactivity and Selectivity within a Strained Architecture: Construction of the [6-6-5-7] Tetracyclic Core of Calyciphylline Alkaloids[J]. JOURNAL OF ORGANIC CHEMISTRY,2012,77(14):6307-6313. |
| APA | Xu, Chen,Wang, Lu,Hao, Xiaojiang,&Wang, David Zhigang.(2012).Tackling Reactivity and Selectivity within a Strained Architecture: Construction of the [6-6-5-7] Tetracyclic Core of Calyciphylline Alkaloids.JOURNAL OF ORGANIC CHEMISTRY,77(14),6307-6313. |
| MLA | Xu, Chen,et al."Tackling Reactivity and Selectivity within a Strained Architecture: Construction of the [6-6-5-7] Tetracyclic Core of Calyciphylline Alkaloids".JOURNAL OF ORGANIC CHEMISTRY 77.14(2012):6307-6313. |
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