| Two new complex triterpenoid saponins from Gledistsia dolavayi Franch. |
| Teng, RW; Ni, W; Wang, DZ; Ding, JK; Chen, CX
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| 2002-09-01
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| 发表期刊 | MAGNETIC RESONANCE IN CHEMISTRY
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| 卷号 | 40期号:9页码:609-613 |
| 摘要 | Two new triterpenoid saponins, gledistside A (1) and gledistside B (2), isolated from the fruits of Gledistsia dolavayi Franch., were characterized as the 3,28-O-bisdesmoside of echinocystic acid acylated with monoterpene carboxylic acids. On the basis of spectroscopic and chemical evidence, their structures were elucidated as 3-O-beta-D-xylopyranosyl-(1 --> 2)-alpha-L-arabinopyranosyl-(1 --> 6)-beta-D-glucopyranosyl-28-O-beta-D-xylopyranosyl-(1 --> 3)-beta-D-xylopyranosyl-(1 --> 4)-[beta-D-galactopyranosyl-(1 --> 2)-alpha-L-rhamnopyranosyl-(1 --> 2)- -(6-O-[2,6-dimethyl-6(S)-hydroxy-2-trans-2,7-octadienoyl])-beta-D-glucopyranosylechinocystic acid (1) and 3-O-beta-D-xylopyranosyl-(1 --> 2)-alpha-L-arabinopyranosyl-(1 --> 6)-beta-D-glucopyranosyl-28-O-beta-D-xylopyranosyl-(1 --> 3)-beta-D-xylopyranosyl-(1 --> 4)-beta-D-galactopyranosyl-(1 --> 2)]-alpha-L-rhamnopyranosyl-(1 --> 2)-6-O-[2-hydroxymethyl-6-methyl-6(S)-hydroxy-2-trans-2,7-octadienoyl])-beta-D-glucopyranosylechinocystic acid (2). The complete H-1 and C-13 assignments of saponins 1 and 2 were achieved on the basis of 2D NMR spectra including HMQC-TOCSY, TOCSY, H-1-H-1 COSY, HMBC, ROESY and HMQC spectra. Copyright (C) 2002 John Wiley Sons, Ltd. |
| 关键词 | Nmr
H-1 Nmr
C-13 Nmr
2d Nmr
Gledistsia Dolavayi Franch.
Leguminosae
Triterpenoid Saponin
Gledistside a
Gledistside b
Nmr Complete Assignments
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| 学科领域 | Chemistry, Multidisciplinary
; Chemistry, Physical
; Spectroscopy
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| DOI | 10.1002/mrc.1061
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| 收录类别 | SCI
; IC
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| 语种 | 英语
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| WOS记录号 | WOS:000177489100010
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| 引用统计 |
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| 文献类型 | 期刊论文
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| 条目标识符 | http://ir.kib.ac.cn/handle/151853/14605
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| 专题 | 植物化学与西部植物资源持续利用国家重点实验室
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| 作者单位 | Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources W China, Yunnan 650204, Peoples R China
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推荐引用方式
GB/T 7714 |
Teng, RW,Ni, W,Wang, DZ,et al. Two new complex triterpenoid saponins from Gledistsia dolavayi Franch.[J]. MAGNETIC RESONANCE IN CHEMISTRY,2002,40(9):609-613.
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| APA |
Teng, RW,Ni, W,Wang, DZ,Ding, JK,&Chen, CX.(2002).Two new complex triterpenoid saponins from Gledistsia dolavayi Franch..MAGNETIC RESONANCE IN CHEMISTRY,40(9),609-613.
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| MLA |
Teng, RW,et al."Two new complex triterpenoid saponins from Gledistsia dolavayi Franch.".MAGNETIC RESONANCE IN CHEMISTRY 40.9(2002):609-613.
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