Shape-persistent phthalocyanine cages

doi:10.1016/j.xcrp.2023.101285

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	Shape-persistent phthalocyanine cages
	Hu,Yiming; Huang,Shaoda; Wayment,Lacey J.; Wu,Jingyi; Xu,Qiucheng; Chang,Tieyan; Chen,Ying-Pin; Li,Xiaonian; Andi,Babak; Chen,Hongxuan; Jin,Yinghua; Zhu,Han; Du,Mingliang; Lu,Shuanglong; Zhang,Wei
	2023
发表期刊	CELL REPORTS PHYSICAL SCIENCE
ISSN	2666-3864
卷号	4 期号:2 页码:101285
摘要	Phthalocyanine (Pc), an electro-redox active moiety, has many attractive properties stemming from its large aromatic system and ability to act as a catalyst in electrochemical reactions, such as the CO2 reduction reaction (CO2RR). However, due to the synthetic chal-lenge related to geometric requirements and poor solubility (strong aggregation), discrete shape-persistent cages consisting of site -iso-lated, readily accessible Pc moieties have not been available. Here, we report the synthesis of Zn-and Ni-metallated Pc-based molecular cages via one-step dynamic spiroborate linkage formation in high yields. The ZnPc cage structure is unambiguously elucidated at the atomic level by single-crystal X-ray diffraction. Moreover, owing to the site-isolated redox-active metal centers, readily accessible intrinsic cavity, and shape-persistent backbone, the Ni-metallated Pc (NiPc) cage exhibits high catalytic efficiency, selectivity, and sta-bility, superior to the non-caged control molecules in electrocata-lytic CO2RR.
关键词	PALLADIUM NANOPARTICLES MOLECULAR CAGE ORGANIC CAGE PERFORMANCE CATALYSTS
学科领域	Chemistry ; Energy & Fuels ; Materials Science ; Physics
DOI	10.1016/j.xcrp.2023.101285
收录类别	SCI
WOS记录号	WOS:000961505700001
引用统计
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/75447
专题	中国科学院昆明植物研究所
推荐引用方式 GB/T 7714	Hu,Yiming,Huang,Shaoda,Wayment,Lacey J.,et al. Shape-persistent phthalocyanine cages[J]. CELL REPORTS PHYSICAL SCIENCE,2023,4(2):101285.
APA	Hu,Yiming.,Huang,Shaoda.,Wayment,Lacey J..,Wu,Jingyi.,Xu,Qiucheng.,...&Zhang,Wei.(2023).Shape-persistent phthalocyanine cages.CELL REPORTS PHYSICAL SCIENCE,4(2),101285.
MLA	Hu,Yiming,et al."Shape-persistent phthalocyanine cages".CELL REPORTS PHYSICAL SCIENCE 4.2(2023):101285.

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