Enantioselective total syntheses of (-)-cephalotaxine and (-)-amathaspiramide F through a key Ir/Cu dual catalysis

doi:10.1039/d3qo00233k

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	Enantioselective total syntheses of (-)-cephalotaxine and (-)-amathaspiramide F through a key Ir/Cu dual catalysis
	Sheng,Peng-Zhen; Li,Lu-Lu; Zhang,Hongbin; Wei,Kun; Yang,Yu-Rong
	2023
发表期刊	ORGANIC CHEMISTRY FRONTIERS
卷号	10 期号:10 页码:2532-2537
摘要	A recently developed Ir/Cu dual catalysed allylation, which could efficiently provide excellent enantio- and diastereoselectivity in the construction of vicinal tertiary and N-substituted quaternary stereogenic centres in one step, is strategically utilised for the first time in the syntheses of two alkaloids-cephalotaxine and amathaspiramide F.
关键词	FORMAL TOTAL-SYNTHESIS ALPHA-AMINO-ACIDS CEPHALOTAXUS ALKALOIDS (+/-)-CEPHALOTAXINE AMATHASPIRAMIDES REARRANGEMENT CONSTRUCTION CYCLIZATIO
学科领域	Chemistry
DOI	10.1039/d3qo00233k
收录类别	SCI
WOS记录号	WOS:000972843100001
引用统计
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/75438
专题	中国科学院昆明植物研究所
推荐引用方式 GB/T 7714	Sheng,Peng-Zhen,Li,Lu-Lu,Zhang,Hongbin,et al. Enantioselective total syntheses of (-)-cephalotaxine and (-)-amathaspiramide F through a key Ir/Cu dual catalysis[J]. ORGANIC CHEMISTRY FRONTIERS,2023,10(10):2532-2537.
APA	Sheng,Peng-Zhen,Li,Lu-Lu,Zhang,Hongbin,Wei,Kun,&Yang,Yu-Rong.(2023).Enantioselective total syntheses of (-)-cephalotaxine and (-)-amathaspiramide F through a key Ir/Cu dual catalysis.ORGANIC CHEMISTRY FRONTIERS,10(10),2532-2537.
MLA	Sheng,Peng-Zhen,et al."Enantioselective total syntheses of (-)-cephalotaxine and (-)-amathaspiramide F through a key Ir/Cu dual catalysis".ORGANIC CHEMISTRY FRONTIERS 10.10(2023):2532-2537.

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