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Discovery of Unusual Sesterterpenoids from Colquhounia coccinea var. mollis and Their Metabolic Implications | |
Jing,Shu-Xi; Fu,Ran; Li,Chun-Huan; Hugelshofer,Cedric L.; Shi,Yi-Ming; Luo,Shi-Hong; Liu,Yan-Chun; Liu,Yan; Li,Sheng-Hong | |
2023 | |
发表期刊 | JOURNAL OF NATURAL PRODUCTS |
ISSN | 1520-6025 |
卷号 | 86期号:11页码:2468-2473 |
摘要 | Three unusual sesterterpenoids featuring unprecedented rearranged colquhounane (C-25) and tetranorcolquhounane (C-21) frameworks, colquhounoids E (1) and F (3) and norcolquhounoid F (2), were isolated from a Lamiaceae medicinal plant Colquhounia coccinea var. mollis. Their structures were elucidated by spectroscopic analysis and quantum chemical calculations. A biomimetic inspired regioselective cyclopropane cleavage was achieved under acidic conditions. The immunosuppressive activities of these new sesterterpenoids were also evaluated. |
关键词 | LEUCOSCEPTRUM-CANUM GLANDULAR TRICHOMES CIRCULAR-DICHROISM HARBOR |
DOI | 10.1021/acs.jnatprod.3c00553 |
收录类别 | SCI |
WOS记录号 | WOS:001109871400001 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.kib.ac.cn/handle/151853/75291 |
专题 | 中国科学院昆明植物研究所 |
推荐引用方式 GB/T 7714 | Jing,Shu-Xi,Fu,Ran,Li,Chun-Huan,et al. Discovery of Unusual Sesterterpenoids from Colquhounia coccinea var. mollis and Their Metabolic Implications[J]. JOURNAL OF NATURAL PRODUCTS,2023,86(11):2468-2473. |
APA | Jing,Shu-Xi.,Fu,Ran.,Li,Chun-Huan.,Hugelshofer,Cedric L..,Shi,Yi-Ming.,...&Li,Sheng-Hong.(2023).Discovery of Unusual Sesterterpenoids from Colquhounia coccinea var. mollis and Their Metabolic Implications.JOURNAL OF NATURAL PRODUCTS,86(11),2468-2473. |
MLA | Jing,Shu-Xi,et al."Discovery of Unusual Sesterterpenoids from Colquhounia coccinea var. mollis and Their Metabolic Implications".JOURNAL OF NATURAL PRODUCTS 86.11(2023):2468-2473. |
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10.1021_acs.jnatprod(2029KB) | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | 浏览 下载 |
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