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Enantioselective Total Synthesis of the Cephalotaxus Alkaloid (-)-Cephalotine A | |
Sheng,Peng-Zhen; Li,Lu-Lu; Ni,Zhi-Bin; Wei,Kun; Yang,Yu-Rong | |
2023 | |
发表期刊 | ORGANIC LETTERS
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ISSN | 1523-7052 |
摘要 | Cephalotine A, a recently isolated Cephalotaxus alkaloid,was firstsynthesized enantioselectively through three critical reactions. SmI2 -mediated radical cyclization of lactone and aldehyde toforge the final ring system, Chang's iridium-catalyzed C-Hamidation to construct pyrrolidone stereoselectively, and Carreria'sdual Ir/amine catalyzed allylation to install the vicinal tertiarystereocenters. |
关键词 | FORMAL TOTAL-SYNTHESIS ALPHA-ALLYLATION UNIFIED STRATEGY NATURAL-PRODUCTS GAMMA-LACTAMS HECK REACTION (+/-)-CEPHALOTAXINE REARRANGEMENT C |
DOI | 10.1021/acs.orglett.3c02097 |
收录类别 | SCI |
WOS记录号 | WOS:001047853100001 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.kib.ac.cn/handle/151853/75283 |
专题 | 中国科学院昆明植物研究所 |
推荐引用方式 GB/T 7714 | Sheng,Peng-Zhen,Li,Lu-Lu,Ni,Zhi-Bin,et al. Enantioselective Total Synthesis of the Cephalotaxus Alkaloid (-)-Cephalotine A[J]. ORGANIC LETTERS,2023. |
APA | Sheng,Peng-Zhen,Li,Lu-Lu,Ni,Zhi-Bin,Wei,Kun,&Yang,Yu-Rong.(2023).Enantioselective Total Synthesis of the Cephalotaxus Alkaloid (-)-Cephalotine A.ORGANIC LETTERS. |
MLA | Sheng,Peng-Zhen,et al."Enantioselective Total Synthesis of the Cephalotaxus Alkaloid (-)-Cephalotine A".ORGANIC LETTERS (2023). |
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