Rearranged Homoadamantane-Type Polycyclic Polyprenylated Acylphloroglucinols from Hypericum pseudohenryi

doi:10.1021/acs.orglett.3c03143

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	Rearranged Homoadamantane-Type Polycyclic Polyprenylated Acylphloroglucinols from Hypericum pseudohenryi
	Jiang,Na-Na; Ye,Yan-Song; Liu,Xia; Wang,Yong-Ling; Xu,Gang
	2023
发表期刊	ORGANIC LETTERS
ISSN	1523-7052
卷号	25 期号:50 页码:8965-8969
摘要	Hypseudohenones A-C (1-3), the first rearranged homoadamantane-type polycyclic polyprenylated acylphloroglucinols, were isolated from Hypericum pseudohenryi. Their structures with an unprecedented tricyclo-[4.3.1.1(3,8)]-undecane-2,4,10-trione core were determined by spectroscopic analysis, quantum-chemical calculations, and X-ray crystallography. A method for determining the relative configuration at C-3 was established by the peak shape of H-28 or J-value of H-3/H-28. Moreover, 2-3 exhibited significant AChE inhibitory activity, and the interactions of 2-3 with AChE were evaluated by molecular docking.
DOI	10.1021/acs.orglett.3c03143
收录类别	SCI
WOS记录号	WOS:001130222900001
引用统计
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/75279
专题	中国科学院昆明植物研究所
推荐引用方式 GB/T 7714	Jiang,Na-Na,Ye,Yan-Song,Liu,Xia,et al. Rearranged Homoadamantane-Type Polycyclic Polyprenylated Acylphloroglucinols from Hypericum pseudohenryi[J]. ORGANIC LETTERS,2023,25(50):8965-8969.
APA	Jiang,Na-Na,Ye,Yan-Song,Liu,Xia,Wang,Yong-Ling,&Xu,Gang.(2023).Rearranged Homoadamantane-Type Polycyclic Polyprenylated Acylphloroglucinols from Hypericum pseudohenryi.ORGANIC LETTERS,25(50),8965-8969.
MLA	Jiang,Na-Na,et al."Rearranged Homoadamantane-Type Polycyclic Polyprenylated Acylphloroglucinols from Hypericum pseudohenryi".ORGANIC LETTERS 25.50(2023):8965-8969.

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