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Structure Revision of Four Classes of Prenylated Aromatic Natural Products Based on a Rule for Diagnostic C-13 NMR Chemical Shifts
Ren,Fu-Cai; Wang,Li-Xia; Lv,Yong-Feng; Hu,Jiang-Miao; Zhou,Jun
2021
发表期刊JOURNAL OF ORGANIC CHEMISTRY
ISSN0022-3263
卷号86期号:16页码:10982-10990
摘要Errors in elucidating the structures of four natural classes of prenylated aromatic compounds with 2,3-epoxy, 2,3-dihydroxy, and cyclization with an ortho-phenolic hydroxyl to give a pyran or furan ring moiety are frequent and inevitable. Based on rigorous literature research and a series of chemical transformation experiments, a rule for the rapid determination of these four classes of prenylated derivates based on C-13 NMR data was formulated, and 57 corrections featuring these fragments were accordingly reported.
关键词ISOPRENYLATED FLAVONOIDS CONSTITUENTS DERIVATIVES ANALOGS
DOI10.1021/acs.joc.0c02409
WOS记录号WOS:000687851300006
引用统计
文献类型期刊论文
条目标识符http://ir.kib.ac.cn/handle/151853/73638
专题中国科学院昆明植物研究所
作者单位1.[Ren, Fu-Cai
2.Lv, Yong-Feng
3.Hu, Jiang-Miao
4.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China
5.Chinese Acad Sci, Kunming Inst Bot, Yunnan Key Lab Nat Med Chem, Kunming 650201, Yunnan, Peoples R China
6.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
7.Yunnan Agr Univ, Coll Food Sci & Technol, Key Lab Pu Er Tea Sci, Minist Educ, Kunming 650201, Yunnan, Peoples R China
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GB/T 7714
Ren,Fu-Cai,Wang,Li-Xia,Lv,Yong-Feng,et al. Structure Revision of Four Classes of Prenylated Aromatic Natural Products Based on a Rule for Diagnostic C-13 NMR Chemical Shifts[J]. JOURNAL OF ORGANIC CHEMISTRY,2021,86(16):10982-10990.
APA Ren,Fu-Cai,Wang,Li-Xia,Lv,Yong-Feng,Hu,Jiang-Miao,&Zhou,Jun.(2021).Structure Revision of Four Classes of Prenylated Aromatic Natural Products Based on a Rule for Diagnostic C-13 NMR Chemical Shifts.JOURNAL OF ORGANIC CHEMISTRY,86(16),10982-10990.
MLA Ren,Fu-Cai,et al."Structure Revision of Four Classes of Prenylated Aromatic Natural Products Based on a Rule for Diagnostic C-13 NMR Chemical Shifts".JOURNAL OF ORGANIC CHEMISTRY 86.16(2021):10982-10990.
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