Synthetic Studies toward Parvistemoline Using Asymmetric Ir/Amine-Catalyzed Allylation

doi:10.1021/acs.joc.1c00390

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	Synthetic Studies toward Parvistemoline Using Asymmetric Ir/Amine-Catalyzed Allylation
	Zheng,Yu; Yang,Hong-Dou ; Wei,Kun ; Yang,Yu-Rong
	2021
发表期刊	JOURNAL OF ORGANIC CHEMISTRY
ISSN	0022-3263
卷号	86 期号:8 页码:6025-6029
摘要	The common, key tricyclic core of stemona alkaloids parvistemonine (1) and parvistemoline (2), whose synthetic efforts have not reported yet, was constructed through a new strategy in which three contiguous stereogenic centers were set by using Carreira's asymmetric Ir/amine-catalyzed allylation of aldehyde with alpha-vinylfurfuryl alcohol and Ellman's sulfinamide chiral auxiliary, respectively. The furan ring was especially designed to act as the precursor of the butyrolactone while establishing the significant chirality.
关键词	ENANTIOSELECTIVE TOTAL-SYNTHESIS ALPHA-ALLYLATION STEMONA ALKALOIDS IRIDIUM
DOI	10.1021/acs.joc.1c00390
WOS记录号	WOS:000641292800054
引用统计
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/73224
专题	中国科学院昆明植物研究所
作者单位	1.[Zheng, Yu 2.Yang, Hong-Dou 3.Wei, Kun 4.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China 5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zheng,Yu,Yang,Hong-Dou,Wei,Kun,et al. Synthetic Studies toward Parvistemoline Using Asymmetric Ir/Amine-Catalyzed Allylation[J]. JOURNAL OF ORGANIC CHEMISTRY,2021,86(8):6025-6029.
APA	Zheng,Yu,Yang,Hong-Dou,Wei,Kun,&Yang,Yu-Rong.(2021).Synthetic Studies toward Parvistemoline Using Asymmetric Ir/Amine-Catalyzed Allylation.JOURNAL OF ORGANIC CHEMISTRY,86(8),6025-6029.
MLA	Zheng,Yu,et al."Synthetic Studies toward Parvistemoline Using Asymmetric Ir/Amine-Catalyzed Allylation".JOURNAL OF ORGANIC CHEMISTRY 86.8(2021):6025-6029.

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