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Enantioselective Iridium-Catalyzed Allylic Alkylation of Racemic Branched Alkyl-Substituted Allylic Acetates with Malonates
Zhang,Tian-Yuan; Deng,Yi; Wei,Kun; Yang,Yu-Rong
2021
Source PublicationORGANIC LETTERS
ISSN1523-7060
Volume23Issue:3Pages:1086-1089
AbstractThe regio- and enantioselective allylic substitution of branched alkyl-substituted allylic acetates employing malonates has been achieved through a process that calls for Krische's pi-allyliridium C,O-benzoate catalyst. The protocol reported herein can be applied to a diverse set of branched alkyl substrates that are generally not well tolerated in the other two types of Ir-catalyzed allylation.T
KeywordDIASTEREO
DOI10.1021/acs.orglett.0c04309
WOS IDWOS:000629001700086
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Document Type期刊论文
Identifierhttp://ir.kib.ac.cn/handle/151853/73137
Collection中国科学院昆明植物研究所
Affiliation1.[Zhang, Tian-Yuan
2.Deng, Yi
3.Wei, Kun
4.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China
5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhang,Tian-Yuan,Deng,Yi,Wei,Kun,et al. Enantioselective Iridium-Catalyzed Allylic Alkylation of Racemic Branched Alkyl-Substituted Allylic Acetates with Malonates[J]. ORGANIC LETTERS,2021,23(3):1086-1089.
APA Zhang,Tian-Yuan,Deng,Yi,Wei,Kun,&Yang,Yu-Rong.(2021).Enantioselective Iridium-Catalyzed Allylic Alkylation of Racemic Branched Alkyl-Substituted Allylic Acetates with Malonates.ORGANIC LETTERS,23(3),1086-1089.
MLA Zhang,Tian-Yuan,et al."Enantioselective Iridium-Catalyzed Allylic Alkylation of Racemic Branched Alkyl-Substituted Allylic Acetates with Malonates".ORGANIC LETTERS 23.3(2021):1086-1089.
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