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Study on the spatial structure of brachystemin C, a new cyclic peptide from Brachystemma calycinum
Wang, C; Zhang, LL; Lu, Y; Zheng, QT; Cheng, YX; Zhou, J; Tan, NH
2004-01-21
发表期刊JOURNAL OF MOLECULAR STRUCTURE
卷号688期号:1-3页码:67-71
摘要A new cyclic octapeptide, brachstemin C (the molecular formula: C38H56N8O9), was isolated from the root of Brachystemma calycinum. The types and sequence of the amino acids of the title compound were confirmed by spectral analyses and X-ray diffraction. The stereochemistry of the title cyclic octapeptide was clarified by X-ray crystallographic study. The cyclic octapeptide backbone contains three beta-turns. Two of them are type I beta-turns and one is type III beta-turn (right-handed 3(10) helix). There are intermolecular hydrogen bonds between the cyclic peptide and the solvent molecules which maintained the steady spatial arrangement in crystal. (C) 2003 Elsevier B.V. All rights reserved.
关键词Cyclic Octapeptide Brachystemin c X-ray Diffraction Spatial Structure
DOI10.1016/j.molstruc.2003.09.012
收录类别SCI
语种英语
WOS记录号WOS:000188093900007
引用统计
被引频次:12[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.kib.ac.cn/handle/151853/24777
专题离退休
作者单位1.Chinese Acad Med Sci, Inst Mat Med, Dept Analyt Chem, Beijing 100050, Peoples R China
2.Peking Union Med Coll, Beijing 100050, Peoples R China
3.Chinese Acad Sci, Kunming Inst Bot, Lab Phytochem, Kunming, Peoples R China
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Wang, C,Zhang, LL,Lu, Y,et al. Study on the spatial structure of brachystemin C, a new cyclic peptide from Brachystemma calycinum[J]. JOURNAL OF MOLECULAR STRUCTURE,2004,688(1-3):67-71.
APA Wang, C.,Zhang, LL.,Lu, Y.,Zheng, QT.,Cheng, YX.,...&Tan, NH.(2004).Study on the spatial structure of brachystemin C, a new cyclic peptide from Brachystemma calycinum.JOURNAL OF MOLECULAR STRUCTURE,688(1-3),67-71.
MLA Wang, C,et al."Study on the spatial structure of brachystemin C, a new cyclic peptide from Brachystemma calycinum".JOURNAL OF MOLECULAR STRUCTURE 688.1-3(2004):67-71.
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