Sensitized photooxidation of furanoeremophilane with singlet oxygen and their biogenetic relationship

doi:10.1080/14786410500185733

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	Sensitized photooxidation of furanoeremophilane with singlet oxygen and their biogenetic relationship
	Li, YS ; Wang, ZT ; Luo, SD ; Li, SS ; Zhu, DY
通讯作者	Sinodlsia@yahoo.com
	2006-07-10
发表期刊	NATURAL PRODUCT RESEARCH
ISSN	1478-6419
卷号	20 期号:8 页码:724-730
摘要	In an attempt to explore the biogenetic relationship of furanoeremophilane derivatives and eremophilan-8 alpha, 12-olides, produced in Ligularia and their structure-activity relationship, we studied the photosensitized oxidation of furanoeremophilane - type sesquiterpenes. Under the condition of several solvents solution Irradiation with a 200 W incandescent lamp of furanoeremophilan-14 beta,6 alpha-olide isolated from Ligularia vellerea, in various solutions with methylene blue, rose bengal, toluidine blue and safranine T gave several products. The products were isolated by chromatographic procedure and their structures were elucidated as eremophilan-14 beta,6 alpha,8 alpha,12-diolide derivatives by NMR, IR and MS methods. A reaction mechanism has been proposed.
关键词	Furanoeremophilane Photosensitized Oxidation Biogenetic Relationship Structure-activity Relationship
学科领域	Chemistry, Applied ; Chemistry, Medicinal
DOI	10.1080/14786410500185733
收录类别	SCI
语种	英语
WOS记录号	WOS:000238074900005
引用统计
文献类型	期刊论文
条目标识符	http://ir.kib.ac.cn/handle/151853/13549
专题	离退休
作者单位	1.Chinese Acad Sci, Inst Mat Med, State Key Lab Drug Res, Shanghai 201203, Peoples R China 2.Shanghai Jiao Tong Univ, Sch Pharm, Dept Nat Med Chem, Shanghai 201203, Peoples R China 3.China Pharmaceut Univ, Dept Pharmacognosy, Nanjing 210038, Peoples R China 4.Chinese Acad Sci, Kunming Inst Bot, Kunming 650204, Peoples R China
推荐引用方式 GB/T 7714	Li, YS,Wang, ZT,Luo, SD,et al. Sensitized photooxidation of furanoeremophilane with singlet oxygen and their biogenetic relationship[J]. NATURAL PRODUCT RESEARCH,2006,20(8):724-730.
APA	Li, YS,Wang, ZT,Luo, SD,Li, SS,&Zhu, DY.(2006).Sensitized photooxidation of furanoeremophilane with singlet oxygen and their biogenetic relationship.NATURAL PRODUCT RESEARCH,20(8),724-730.
MLA	Li, YS,et al."Sensitized photooxidation of furanoeremophilane with singlet oxygen and their biogenetic relationship".NATURAL PRODUCT RESEARCH 20.8(2006):724-730.

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